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Title:Effect of multi-directional forging on microstructure and properties of V3TiNi0.56Al0.2 hydrogen storage alloy for negative electrode material of new energy automotive batteries
Authors: Wang Guanggang1 Ge Dongyuan2 
Unit: (1.School of Transportation Shangqiu Polytechnic Shangqiu 476000 China 2.School of Mechanical and Automotive Engineering   Guangxi University of Science and Technology Liuzhou 545006 China) 
KeyWords: V3TiNi0.56Al0.2 hydrogen storage alloy  multi-directional forging  microstructure  hydrogen absorption and desorption properties  charge-discharge cycle stability 
ClassificationCode:TG146.2
year,vol(issue):pagenumber:2025,50(4):7-12
Abstract:

 V3TiNi0.56Al0.2  hydrogen storage alloy is a vanadium-based hydrogen storage alloy with great development prospects. 

Taking V3TiNi0.56Al0.2 hydrogen storage alloy as the research object, the V3TiNi0.56Al0.2 hydrogen storage alloy  sample was forged by multi-directional forging method, and a comparative analysis was conducted on the microstructure, hydrogen absorption and desorption properties, and charge-discharge cycle stability with those of the billet samples before forging. The results show that the multi-directional forging refines the grain inside the V3TiNi0.56Al 0.2 hydrogen storage alloy and improves its hydrogen absorption and desorption 
properties and charge-discharge cycle stability. 
The average grain size of V3TiNi0.56Al0.2 hydrogen storage alloy after multi-directional forging is 13 μm, the maximum hydrogen absorption capacity is 2.854 wt.%, the maximum discharge capacity reaches 337.1 mAh·g-1 after the first charge-discharge cycle, and the discharge capacity decay rate is 15.0% after 1000 charge-discharge cycles. 
 
Compared with the billet sample before forging, the average grain of V3TiNi0.56Al0.2 hydrogen storage alloy sample after multi-directional forging decreases by 35 μm, and the maximum hydrogen absorption capacity increases by 1.836%, the maximum discharge capacity increases by 181.4  mAh·g-1, and the discharge capacity decay rate decreases by 56.6%. 
 
Funds:
基金项目:河南省高等学校重点科研项目(24B470006)
AuthorIntro:
作者简介:王广钢(1986-),男,硕士,讲师
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