Abstract:
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In order to improve the mechanical properties of high entropy alloy (Fe50Ni30Co10Cr10) with non-equal atomic ratio, B element was added to the alloy as a clearance enhancement atom. After the deformation treatment and annealing, the precise control of the alloy microstructure was realized, and the recrystallization transformation processes of the alloy after annealing at different times and temperatures were analyzed. The results show that the addition of B element to FeCoCrNi high entropy alloy causes a small drop in the temperature of σ phase, and with the gradual decreasing of the temperature, Cr5B3 phase is formed at 574 ℃. Furthermore, the as-cast sample contains two phase structures with the fcc matrix phase and the Cr5B3 second phase. In the state of small deformation, the grain shape is mainly dendritic, and the intragranular structure slips to form the obvious step shape. After the deformation reaches 50%, the grains are obvious elongated to form the deformation structure of the twisted band, and the dendritic structure gradually changes into a flat structure. With the increasing of deformation amount, the grain size gradually decreases, and the grains are obviously refined. When the annealing time reaches 30 min, the grain size formed is significantly different from the grain size annealed at the annealing time of 10 min without the condition of grain growth, and a large number of hcp lath structures are also formed in the equiaxed grains.
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Funds:
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河南省科技攻关计划项目(142102310526);河南省教育厅项目(201706207)
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AuthorIntro:
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作者简介:刘世平(1979-),男,硕士,讲师,E-mail:liushiping79@163.com
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Reference:
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[1]陈扬, 涂坚, 张琰斌, 等. 形变和退火对Fe(47)Mn(30)Co(10)Cr(10)B3间隙高熵合金微观组织结构演变的影响[J]. 材料研究学报, 2021, 35(2): 143-153. Chen Y, Tu J, Zhang Y B, et al. Effect of deformation and annealing on microstructure evolution of Fe(47)Mn(30)Co(10)Cr(10)B3 interstitial high entropy alloy [J].Journal of Materials Research, 2021, 35(2): 143-153. [2]杨恬, 许军锋, 李卓. 高强韧共晶高熵合金的研究进展[J]. 金属热处理, 2021, 46(2): 1-7. Yang T, Xu J F, Li Z. Research progress of high strength and toughness eutectic high entropy alloy[J]. Heat Treatment of Metals, 2021, 46(2): 1-7. [3]黄蕾, 郝雪卉, 赵性川, 等. 高温退火对AlCrFeNiTi高熵合金组织和性能的影响[J]. 材料热处理学报, 2021, 42(1): 91-96. Huang L, Hao X H, Zhao X C, et al. Effect of high temperature annealing on microstructure and properties of AlCrFeNiTi high entropy alloy [J].Journal of Materials and Heat Treatment, 2021, 42(1): 91-96. [4]薛彦均, 尉文超, 王毛球, 等. 退火温度对FeMoCrVTiSix高熵合金组织及力学性能的影响[J]. 金属热处理, 2020, 45(12): 7-12. Xue Y J, Wei W C, Wang M Q, et al. Effect of annealing temperature on microstructure and mechanical properties of FeCoCrVTiSix high entropy alloy [J].Heat Treatment of Metals, 2020, 45(12): 7-12. [5]Wang J L, Huang M H, Xi X H, et al. Characteristics of nucleation and transformation sequence in deformation-induced martensitic transformation [J]. Materials Characterization, 2020, 163: 110234 [6]He Z F, Jia N, Ma D, et al. Joint contribution of transformation and twinning to the high strength-ductility combination of a FeMnCoCr high entropy alloy at cryogenic temperatures [J]. Materials Science and Engineering:A, 2019, A759: 437-447. [7]吕昭平, 蒋虽合, 何骏阳, 等. 先进金属材料的第二相强化[J]. 金属学报, 2016, 52(10): 1183-1198. Lu Z, Jiang S, He J Y, et al. Second phase strengthening in advanced metal materials [J]. Acta Metallurgica Sinica, 2016, 52(10): 1183-1198. [8]Wang Z, Baker I, Cai Z, et al. The effect of interstitial carbon on the mechanical properties and dislocation substructure evolution in Fe40. 4Ni11. 3Mn34. 8Al7. 5Cr6 high entropy alloys [J]. Acta Materialia, 2016, 120: 228-239. [9]Guo W, Su J, Lu W, et al. Dislocation-induced breakthrough of strength and ductility trade-off in a non-equiatomic high-entropy alloy [J]. Acta Materialia, 2020, 185: 45-54. [10]李航, 李杰, 褚延朋, 等. 冷轧退火对FeMnCoCrAl高熵合金组织和力学性能的影响[J]. 金属热处理, 2020, 45(11): 105-114. Li H, Li J, Chu Y P, et al. Effect of cold rolling annealing on microstructure and mechanical properties of high entropy FeMnCoCrAl alloy [J].Heat Treatment of Metals, 2020, 45(11): 105-114. [11]李延超, 李来平, 高选乔, 等. 难熔高熵合金研究进展[J]. 稀有金属材料与工程, 2020, 49(12): 4365-4372. Li Y C, Li L P, Gao X Q, et al. Research progress of refractory high entropy alloys[J]. Rare Metal Materials and Engineering, 2020, 49(12): 4365-4372. [12]王文文, 田权伟, 王轶农. 退火对冷轧Al(0.2)CoCrFe2Ni高熵合金组织和力学性能的影响[J]. 金属热处理, 2020, 45(11): 132-138. Wang W W, Tian Q W, Wang Y N. Effect of annealing on microstructure and mechanical properties of cold-rolled Al(0.2)-CoCrFe2Ni high entropy alloy [J].Heat Treatment of Metals, 2020, 45(11): 132-138. [13]李安敏, 王美华, 史君佐, 等. 锻造对FeMnCrCoNi高熵合金组织与性能的影响[J]. 锻压技术, 2019, 44(2): 173-181. Li A M, Wang M H, Shi J Z, et al. Effect of forging on microstructure and properties of high entropy FeMnCrCoI alloy [J]. Forging & Stamping Technology, 2019, 44(2): 173-181. [14]Lei Z F, Wu Y, He J Y, et al. Snoek-type damping performance in strong and ductile high-entropy alloys [J]. Science Advances, 2020, 6(25): eaba7802. [15]Seol J B, Bae J W, Li Z, et al. Boron doped ultrastrong and ductile high-entropy alloys [J]. Acta Materialia, 2018, 151: 366-376.
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